had, at some point in their careers, been “reprimanded, placed on probation, suspended or banned from practicing law by the State Bar.” Although Reaves was more competent, he had few resources to reinvestigate the case, and his writ introduced no new exculpatory evidence: nothing further about Webb, or the reliability of the eyewitness testimony, or the credibility of the medical experts. It focussed primarily on procedural questions, such as whether the trial court erred in its instructions to the jury.

The Texas Court of Criminal Appeals was known for upholding convictions even when overwhelming exculpatory evidence came to light. In 1997, DNA testing proved that sperm collected from a rape victim did not match Roy Criner, who had been sentenced to ninety-nine years for the crime. Two lower courts recommended that the verdict be overturned, but the Court of Criminal Appeals upheld it, arguing that Criner might have worn a condom or might not have ejaculated. Sharon Keller, who is now the presiding judge on the court, stated in a majority opinion, “The new evidence does not establish innocence.” In 2000, George W. Bush pardoned Criner. (Keller was recently charged with judicial misconduct, for refusing to keep open past five o’clock a clerk’s office in order to allow a last-minute petition from a man who was executed later that night.)

On October 31, 1997, the Court of Criminal Appeals denied Willingham’s writ. After Willingham filed another writ of habeas corpus, this time in federal court, he was granted a temporary stay. In a poem, Willingham wrote, “One more chance, one more strike / Another bullet dodged, another date escaped.”

Willingham was entering his final stage of appeals. As his anxieties mounted, he increasingly relied upon Gilbert to investigate his case and for emotional support. “She may never know what a change she brought into my life,” he wrote in his diary. “For the first time in many years she gave me a purpose, something to look forward to.”

As their friendship deepened, he asked her to promise him that she would never disappear without explanation. “I already have that in my life,” he told her.

Together, they pored over clues and testimony. Gilbert says that she would send Reaves leads to follow up, but although he was sympathetic, nothing seemed to come of them. In 2002, a federal court of appeals denied Willingham’s writ without even a hearing. “Now I start the last leg of my journey,” Willingham wrote to Gilbert. “Got to get things in order.”

He appealed to the U.S. Supreme Court, but in December, 2003, he was notified that it had declined to hear his case. He soon received a court order announcing that “the Director of the Department of Criminal Justice at Huntsville, Texas, acting by and through the executioner designated by said Director … is hereby DIRECTED and COMMANDED, at some hour after 6:00 P.M. on the 17th day of February, 2004, at the Department of Criminal Justice in Huntsville, Texas, to carry out this sentence of death by intravenous injection of a substance or substances in a lethal quantity sufficient to cause the death of said Cameron Todd Willingham.”

Willingham wrote a letter to his parents. “Are you sitting down?” he asked, before breaking the news. “I love you both so much,” he said.

His only remaining recourse was to appeal to the governor of Texas, Rick Perry, a Republican, for clemency. The process, considered the last gatekeeper to the executioner, has been called by the U.S. Supreme Court “the ‘fail safe’ in our criminal justice system.”

One day in January, 2004, Dr. Gerald Hurst, an acclaimed scientist and fire investigator, received a file describing all the evidence of arson gathered in Willingham’s case. Gilbert had come across Hurst’s name and, along with one of Willingham’s relatives, had contacted him, seeking his help. After their pleas, Hurst had agreed to look at the case pro bono, and Reaves, Willingham’s lawyer, had sent him the relevant documents, in the hope that there were grounds for clemency.

Hurst opened the file in the basement of his house in Austin, which served as a laboratory and an office, and was cluttered with microscopes and diagrams of half-finished experiments. Hurst was nearly six and a half feet tall, though his stooped shoulders made him seem considerably shorter, and he had a gaunt face that was partly shrouded by long gray hair. He was wearing his customary outfit: black shoes, black socks, a black T-shirt, and loose-fitting black pants supported by black suspenders. In his mouth was a wad of chewing tobacco.

A child prodigy who was raised by a sharecropper during the Great Depression, Hurst used to prowl junkyards, collecting magnets and copper wires in order to build radios and other contraptions. In the early sixties, he received a Ph.D. in chemistry from Cambridge University, where he started to experiment with fluorine and other explosive chemicals, and once detonated his lab. Later, he worked as the chief scientist on secret weapons programs for several American companies, designing rockets and deadly fire bombs—or what he calls “god-awful things.” He helped patent what has been described, with only slight exaggeration, as “the world’s most powerful nonnuclear explosive”: an Astrolite bomb. He experimented with toxins so lethal that a fraction of a drop would rot human flesh, and in his laboratory he often had to wear a pressurized moon suit; despite such precautions, exposure to chemicals likely caused his liver to fail, and in 1994 he required a transplant. Working on what he calls “the dark side of arson,” he retrofitted napalm bombs with Astrolite, and developed ways for covert operatives in Vietnam to create bombs from local materials, such as chicken manure and sugar. He also perfected a method for making an exploding T-shirt by nitrating its fibres.

His conscience eventually began pricking him. “One day, you wonder, What the hell am I doing?” he recalls. He left the defense industry, and went on to invent the Mylar balloon, an improved version of Liquid Paper, and Kinepak, a kind of explosive that reduces the risk of accidental detonation. Because of his extraordinary knowledge of fire and explosives, companies in civil litigation frequently sought his help in determining the cause of a blaze. By the nineties, Hurst had begun devoting significant time to criminal-arson cases, and, as he was exposed to the methods of local and state fire investigators, he was shocked by what he saw.

Many arson investigators, it turned out, had only a high-school education. In most states, in order to be certified, investigators had to take a forty-hour course on fire investigation, and pass a written exam. Often, the bulk of an investigator’s training came on the job, learning from “old-timers” in the field, who passed down a body of wisdom about the telltale signs of arson, even though a study in 1977 warned that there was nothing in “the scientific literature to substantiate their validity.”

In 1992, the National Fire Protection Association, which promotes fire prevention and safety, published its first scientifically based guidelines to arson investigation. Still, many arson investigators believed that what they did was more an art than a science—a blend of experience and intuition. In 1997, the International Association of Arson Investigators filed a legal brief arguing that arson sleuths should not be bound by a 1993 Supreme Court decision requiring experts who testified at trials to adhere to the scientific method. What arson sleuths did, the brief claimed, was “less scientific.” By 2000, after the courts had rejected such claims, arson investigators increasingly recognized the scientific method, but there remained great variance in the field, with many practitioners still relying on the unverified techniques that had been used for generations. “People investigated fire largely with a flat-earth approach,” Hurst told me. “It looks like arson—therefore, it’s arson.” He went on, “My view is you have to have a scientific basis. Otherwise, it’s no different than witch-hunting.”

In 1998, Hurst investigated the case of a woman from North Carolina named Terri Hinson, who was charged with setting a fire that killed her seventeen-month-old son, and faced the death penalty. Hurst ran a series of experiments re-creating the conditions of the fire, which suggested that it had not been arson, as the investigators had claimed; rather, it had started accidentally, from a faulty electrical wire in the attic. Because of this research, Hinson was freed. John Lentini, a fire expert and the author of a leading scientific textbook on arson, describes Hurst as “brilliant.” A Texas prosecutor once told the Chicago Tribune, of Hurst, “If he says it was an arson fire, then it was. If he says it wasn’t, then it wasn’t.”

Hurst’s patents yielded considerable royalties, and he could afford to work pro bono on an arson case for months, even years. But he received the files on Willingham’s case only a few weeks before Willingham was scheduled to be executed. As Hurst looked through the case records, a statement by Manuel Vasquez, the state deputy fire marshal, jumped out at him. Vasquez had testified that, of the roughly twelve hundred to fifteen hundred fires he had investigated, “most all of them” were arson. This was an oddly high estimate; the Texas State Fire Marshals Office typically found arson in only fifty per cent of its cases.

Hurst was also struck by Vasquez’s claim that the Willingham blaze had “burned fast and hot” because of a liquid accelerant. The notion that a flammable or combustible liquid caused flames to reach higher temperatures had been repeated in court by arson sleuths for decades. Yet the theory was nonsense: experiments have proved that wood and gasoline-fuelled fires burn at essentially the same temperature.

Vasquez and Fogg had cited as proof of arson the fact that the front door’s aluminum threshold had melted.

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